General Chemistry 10th Edition by Darrell Ebbing – Test Bank
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Sample Test
Chapter 3 – Calculations with Chemical Formulas and Equations
1. The
molecular formula of a particular solid is C8H6O8. Its molecular mass is
2. A)
352 amu.
3. B)
118 amu.
4. C)
364 amu.
5. D)
230 amu.
6. E)
226 amu.
ANS:
D
PTS:
1
DIF:
easy
REF: 3.1
OBJ: Calculate the formula
mass from a formula. (Example 3.1)
TOP: stoichiometry | mass and
moles of substance
KEY: molecular mass
MSC: general chemistry
2. The
hydrocarbon heptane has the structural formula CH3(CH2)5CH3. What is the
molecular mass of this hydrocarbon?
3. A) 2
amu.
4. B)
009980 amu.
5. C) 17
amu.
6. D)
01160 amu.
7. E) 2
amu.
ANS:
A
PTS:
1
DIF:
easy
REF: 3.1
OBJ: Calculate the formula
mass from a formula.
TOP: stoichiometry | mass and
moles of substance
3. A
single molecule of polystryene has the repeating unit -[CH2CH(C6H5)]n-, where n
is the number of repeating units. What is the value of n if the molecular
mass of a single polymer chain is amu?
4. A)
5. B)
6. C)
7. D)
8. E)
ANS:
A
PTS:
1
DIF: moderate
REF: 3.1
OBJ: Calculate the formula
mass from a formula.
TOP: stoichiometry | mass and
moles of substance
4. The
formula mass of aluminum oxalate, Al2(C2O4)3, is
5. A)
140 amu.
6. B)
318 amu.
7. C)
283 amu.
8. D)
213 amu.
9. E)
185 amu.
ANS:
B
PTS:
1
DIF:
easy
REF: 3.1
OBJ: Calculate the formula
mass from a formula. (Example 3.1)
TOP: stoichiometry | mass and
moles of
substance
KEY: formula mass
MSC: general chemistry
5. The
formula mass of zinc acetate trihydrate, Zn(CH3COO)2 • 3H2O, is
6. A)
321 amu.
7. B)
184 amu.
8. C)
268 amu.
9. D)
238 amu.
10. E)
114 amu.
ANS:
D
PTS:
1
DIF:
easy REF:
3.1
OBJ: Calculate the formula
mass from a formula. (Example 3.1)
TOP: stoichiometry | mass and
moles of
substance
KEY: formula mass
MSC: general chemistry
6. The
fully hydrated form of sodium sulfate is the decahydrate, Na2SO4 • 10H2O.
When heated the hydrated salt loses water. How many water molecules are
found per formula unit in a partially dehydrated sample of sodium sulfate with
a formula mass of 160.1 amu (i.e. find n for Na2SO4 • nH2O)?
7. A) 1
waters.
8. B) 5
waters.
9. C) 3
waters.
10. D) 4
waters.
11. E) 7
waters.
ANS:
A
PTS:
1
DIF:
moderate
REF: 3.1
OBJ: Calculate the formula
mass from a formula.
TOP: stoichiometry | mass and
moles of substance
7. What
is the molecular mass of cycloheptane, C7H14?
8. A) 02
amu
9. B) 19
amu
10. C) 08
amu
11. D) 19
amu
12. E) 12
amu
ANS:
D
PTS:
1
DIF:
easy
REF: 3.1
OBJ: Calculate the formula
mass from a formula. (Example 3.1)
TOP: stoichiometry | mass and
moles of
substance
KEY: molecular mass
MSC: general chemistry
8. What
is the formula mass of strontium phosphate, Sr3(PO4)2?
9. A) 83
amu
10. B) 83
amu
11. C) 59
amu
12. D) 66
amu
13. E) 80
amu
ANS:
E
PTS:
1
DIF:
easy
REF: 3.1
OBJ: Calculate the formula
mass from a formula. (Example 3.1)
TOP: stoichiometry | mass and
moles of
substance
KEY: formula mass
MSC: general chemistry
9. What
is the molecular mass of the hydrocarbon styrene (shown in the figure)?
104.
A) 1 amu.
105.
B) 1 amu.
106.
C) 1 amu.
107.
D) 0 amu.
108.
E) 1 amu.
ANS:
A
PTS:
1
DIF:
easy REF:
3.1
OBJ: Calculate the formula
mass from molecular models. (Example 3.2)
TOP: stoichiometry | mass and
moles of
substance
KEY: molecular mass
MSC: general chemistry
10. What
is the molar mass of ammonium sulfite, (NH4)2SO3?
11. A) 98
g/mol
12. B)
116 g/mol
13. C) 55
g/mol
14. D)
180 g/mol
15. E) 84
g/mol
ANS:
B
PTS:
1
DIF:
easy
REF: 3.2
OBJ: Understand how the
molar mass is related to the formula weight of a substance.
TOP: stoichiometry | mass and
moles of
substance
KEY: formula mass
MSC: general chemistry
11. What
is the molar mass of zinc sulfate heptahydrate, ZnSO4 • 7H2O?
12. A)
g/mol
13. B)
288 g/mol
14. C)
384 g/mol
15. D)
162 g/mol
16. E)
582 g/mol
ANS:
B
PTS:
1
DIF:
easy
REF: 3.2
OBJ: Understand how the
molar mass is related to the formula weight of a substance.
TOP: stoichiometry | mass and
moles of
substance
KEY: formula mass
MSC: general chemistry
12. Plastic
wrap can be made from poly(vinylidene chloride). A single poly(vinylidene
chloride) strand has the general formula -(CH2CHCl)n-, where n ranges
from 10,000 to 100,000. What is the molar mass of a single
poly(vinylidene chloride) molecule containing repeating units?
13. A)
g/mol
14. B)
g/mol
15. C)
g/mol
16. D)
g/mol
17. E)
g/mol
ANS:
A
PTS:
1
DIF:
easy
REF: 3.2
OBJ: Understand how the
molar mass is related to the formula weight of a substance.
TOP: stoichiometry | mass and
moles of substance
13. The
dicarboxylic acid potassium hydrogen pthalate (shown in the figure) is used to
standardize solutions of strong base. What is the molar mass of this
compound?
204.
A) 2 g/mol
205.
B) 2 g/mol
206.
C) 9 g/mol
207.
D) 08 g/mol
208.
E) 2 g/mol
ANS:
A
PTS:
1
DIF:
easy
REF: 3.2
OBJ: Understand how the
molar mass is related to the formula weight of a substance.
TOP: stoichiometry | mass and
moles of substance
14. What
is the molar mass of the solid C8H12N2O4?
15. A)
172 g/mol
16. B)
136 g/mol
17. C)
200 g/mol
18. D)
106 g/mol
19. E)
188 g/mol
ANS:
C
PTS:
1
DIF: easy
REF: 3.2
OBJ: Understand how the
molar mass is related to the formula weight of a substance.
TOP: stoichiometry | mass and
moles of
substance
KEY: molecular mass
MSC: general chemistry
15. A
1.067 g sample of an element contains 5.062 ´ 1021
atoms. What is the element symbol?
16. A) I
17. B) Ag
18. C) La
19. D) Pd
20. E) Rh
ANS:
A
PTS:
1
DIF:
moderate
REF: 3.2
OBJ: Understand how the
molar mass is related to the formula weight of a substance.
TOP: stoichiometry | determining
chemical formulas
16. Monodisperse
polyacrylonitrile contains molecules with the general formula -(CH2CHCN)n-,
where n is typically greater than 10,000. Given that a sample of monodisperse
polyacrilonitrile weighs 197.4 g and contains molecules of
-(CH2CHCN)n-, calculate n.
17. A)
18. B)
19. C)
20. D)
21. E)
ANS:
A
PTS:
1
DIF: difficult
REF: 3.2
OBJ: Understand how the
molar mass is related to the formula weight of a substance.
TOP: stoichiometry | mass and
moles of substance
17. Monodisperse
polyacrylonitrile contains molecules with the general formula -(CH2CHCN)n-,
where n is typically greater than 10,000. Given that a sample of monodisperse
polyacrylonitrile weighs 252.6 g and contains molecules of
-(CH2CHCN)n-, what is the molar mass of the polymer?
18. A)
g/mol
19. B)
g/mol
20. C)
g/mol
21. D)
g/mol
22. E)
g/mol
ANS:
E
PTS:
1
DIF: difficult REF:
3.2
OBJ: Understand how the
molar mass is related to the formula weight of a substance.
TOP: stoichiometry | mass and
moles of substance
18. An
atom of an element weighs 3.00 ´
10–23 g. What is the atomic mass of this element in atomic mass units?
19. A) 4
amu
20. B) 5
amu
21. C) 9
amu
22. D) 1
amu
23. E) 3
amu
ANS:
D
PTS:
1
DIF:
easy
REF: 3.2
OBJ: Calculate the mass of
atoms and molecules. (Example 3.3)
TOP: stoichiometry | mass and moles
of substance
KEY: mole | mole
calculations
MSC: general chemistry
19. What
is the mass in grams of one propene, C3H6, molecule?
20. A) 99
´
10–23 g
21. B) 53
´ 1025
g
22. C) 0
g
23. D) 0
g
24. E) 99
´
10–23 g
ANS:
A PTS:
1
DIF:
easy
REF: 3.2
OBJ: Calculate the mass of
atoms and molecules. (Example 3.3)
TOP: stoichiometry | mass and
moles of substance
KEY: mole | mole
calculations
MSC: general chemistry
20. What
is the mass of oxygen in grams found in one molecule of the compound C7H8O4?
21. A) g
22. B) g
23. C) g
24. D) g
25. E)
156 g
ANS:
A
PTS:
1
DIF:
moderate
REF: 3.2
OBJ: Calculate the mass of
atoms and molecules. (Example 3.3)
TOP: stoichiometry | mass and
moles of substance
21. Which
of the following compounds contains the largest number of atoms?
22. A) 0
mol of K2S
23. B) 0
mol of NH3
24. C) 0
mol of H2SO4
25. D) 0
mol of HCl
26. E) 0
mol of CH3COCl
ANS:
C
PTS:
1
DIF:
easy
REF: 3.2
OBJ: Perform calculations
using the mole.
TOP: stoichiometry | mass and
moles of substance
KEY: mole | mole
calculations
MSC: general chemistry
22. How
many atoms of carbon are there in 0.51 mol of procaine, C13H20N2O2, a “pain
killer” used by dentists?
23. A) 6 ´ 1023
24. B) 3 ´ 1024
25. C) 0 ´ 1024
26. D) 1 ´ 1023
27. E) 6 ´ 1024
ANS:
C
PTS:
1
DIF: easy
REF: 3.2
OBJ: Perform calculations
using the mole.
TOP: stoichiometry | mass and
moles of substance
KEY: mole | mole
calculations
MSC: general chemistry
23. A
sample of ammonium phosphite, (NH4)3PO3, contains 0.909 mol of hydrogen atoms.
The number of moles of oxygen atoms in the sample is
24. A)
227 mol.
25. B)
0909 mol.
26. C)
300 mol.
27. D)
227 mol.
28. E) 00
mol.
ANS:
A
PTS:
1
DIF:
easy
REF: 3.2
OBJ: Perform calculations
using the mole.
TOP: stoichiometry | mass and
moles of substance
24. A
sample of gallium(III) sulfite, Ga2(SO3)3, contains 1.95 mol of sulfite ions.
The number of moles of gallium(III) ions in the sample is
25. A) 30
mol.
26. B) 92
mol.
27. C) 95
mol.
28. D) 84
mol.
29. E) 90
mol.
ANS:
A
PTS:
1
DIF:
easy
REF: 3.2
OBJ: Perform calculations
using the mole.
TOP: stoichiometry | mass and
moles of substance
25. Sorbose,
C6H12O6, is used in making vitamin C. A sorbose sample containing 96.0 g
of carbon atoms also contains ____ g of hydrogen atoms.
26. A) 2
27. B) 1
28. C) 15
´ 103
29. D) 0
30. E) 99
ANS:
B
PTS:
1
DIF:
moderate
REF: 3.2
OBJ: Perform calculations
using the mole.
TOP: stoichiometry | mass and
moles of substance
KEY: mole | mole
calculations
MSC: general chemistry
26. Consider
the following three samples.
27. A
sample containing 180 g glucose (C6H12O6)
28. A sample
containing 90 g glucose and 90 g fructose (C6H12O6)
29. A
sample containing 180 g fructose
Which statement is correct?
1. A)
All three samples have the same number of hydrogen atoms.
2. B)
Both samples A and C have the same number of hydrogen atoms, but more than in
sample B.
3. C)
Sample B has more hydrogen atoms than sample A or sample C.
4. D)
Sample C has more hydrogen atoms than sample A or sample B
5. E)
Sample A has more hydrogen atoms than sample B or sample C.
ANS:
A
PTS:
1
DIF: difficult
REF: 3.2
OBJ: Perform calculations
using the mole.
TOP: stoichiometry | determining
chemical formulas
KEY: mole | mole
calculations
MSC: general chemistry
27. Styrene’s
empirical formula is CH. What mass of styrene contains 7.89 ´ 1021 atoms of
hydrogen? The molar mass of styrene is 104 g/mol.
28. A)
105 g
29. B)
170 g
30. C) 36
g
31. D)
157 g
32. E)
0131 g
ANS:
B
PTS:
1
DIF: moderate
REF: 3.2
OBJ: Convert from moles of
substance to grams of substance. (Example 3.4)
TOP: stoichiometry | mass and
moles of substance
KEY: mole | mole
calculations
MSC: general chemistry
28. What
is the mass of oxygen atoms in 0.305 mol Fe(CO)5?
29. A) 0
g
30. B) 7
g
31. C) 4
g
32. D) 88
g
33. E) 3
g
ANS:
C
PTS:
1
DIF:
moderate
REF: 3.2
OBJ: Convert from moles of
substance to grams of substance. (Example 3.4)
TOP: stoichiometry | mass and
moles of substance
KEY: mole | mole
calculations
MSC: general chemistry
29. What
is the mass in grams of 0.699 mol of glucose, C6H12O6?
30. A)
00388 g
31. B) 1
g
32. C)
126 g
33. D) 0
g
34. E)
258 g
ANS:
C
PTS:
1
DIF:
easy
REF: 3.2
OBJ: Convert from moles of
substance to grams of substance. (Example 3.4)
TOP: stoichiometry | mass and
moles of substance
KEY: mole | mole
calculations
MSC: general chemistry
30. Which
one of the following samples has the greatest mass?
31. A) 39
mol of camphor, C10H16O
32. B) 1
mol of ammonia, NH3
33. C) 2
mol of krypton, Kr
34. D) 6
mol of iodine vapor, I2
35. E) 8
mol of formaldehyde, CH2O
ANS:
D
PTS:
1
DIF:
moderate
REF: 3.2
OBJ: Convert from moles of
substance to grams of substance. (Example 3.4)
TOP: stoichiometry | mass and
moles of substance
KEY: mole | mole calculations
MSC: general chemistry
31. Which
of the following contains the greatest mass of oxygen atoms?
32. A) 6
mol CoSO4 • 7H2O
33. B) 3
mol KHSO4
34. C) 2
mol K2Cr2O7
35. D) 3
mol H2O2
36. E) 3
mol Na2S2O3
ANS:
B
PTS:
1
DIF:
easy
REF: 3.2
OBJ: Convert from moles of
substance to grams of substance. (Example 3.4)
TOP: stoichiometry | mass and
moles of substance
KEY: mole | mole
calculations
MSC: general chemistry
32. Calculate
the number of moles of bromine present in 14.5 mL of Br2(l), whose density is
3.12 g/mL.
33. A) 53
mol
34. B)
181 mol
35. C)
566 mol
36. D)
091 mol
37. E)
283 mol
ANS:
E
PTS:
1
DIF:
moderate REF:
3.2
OBJ: Convert from grams of
substance to moles of substance. (Example 3.5)
TOP: stoichiometry | mass and
moles of substance
KEY: mole | mole
calculations
MSC: general chemistry
33. How
many moles of hexachlorobenzene, C6Cl6, are in 4.45 g of C6Cl6?
34. A)
0208 mol
35. B) 27
´ 103
mol
36. C)
0618 mol
37. D)
0156 mol
38. E)
0322 mol
ANS:
D
PTS:
1
DIF:
easy
REF: 3.2
OBJ: Convert from grams of
substance to moles of substance. (Example 3.5)
TOP: stoichiometry | mass and
moles of substance
KEY: mole | mole
calculations
MSC: general chemistry
34. How
many moles of iron atoms are contained in 4.39 g of iron?
35. A)
245 mol
36. B)
0579 mol
37. C)
0786 mol
38. D)
122 mol
39. E)
169 mol
ANS:
C
PTS:
1
DIF:
easy
REF: 3.2
OBJ: Convert from grams of
substance to moles of substance. (Example 3.5)
TOP: stoichiometry | mass and
moles of substance
KEY: mole | mole
calculations
MSC: general chemistry
35. How
many moles of pentane, C5H12, are contained in a 11-g sample?
36. A) 18
mol
37. B) 15
mol
38. C) 26
mol
39. D) 4
mol
40. E) 1
mol
ANS:
B
PTS:
1
DIF:
easy
REF: 3.2
OBJ: Convert from grams of
substance to moles of substance. (Example 3.5)
TOP: stoichiometry | mass and
moles of substance
KEY: mole | mole
calculations
MSC: general chemistry
36. Sodium
cyclamate, C6H11NHSO3Na, was used at one time as an artificial sweetener.
C6H11NHSO3Na has a molecular mass of 201.2 g/mol. How many moles of sodium
cyclamate are contained in a 67.6-g sample?
37. A)
211 mol
38. B)
193 mol
39. C)
336 mol
40. D)
307 mol
41. E)
13,600 mol
ANS:
C
PTS:
1
DIF:
easy
REF: 3.2
OBJ: Convert from grams of
substance to moles of substance. (Example 3.5)
TOP: stoichiometry | mass and
moles of substance
KEY: mole | mole calculations
MSC: general chemistry
37. How
many moles of silver are contained in 7.00 kg of silver?
38. A) 9
mol
39. B) 9 ´ 101 mol
40. C) 9 ´ 10–3 mol
41. D) 9 ´ 103 mol
42. E) 9 ´ 10–1 mol
ANS:
A
PTS:
1
DIF: easy
REF: 3.2
OBJ: Convert from grams of
substance to moles of substance. (Example 3.5)
TOP: stoichiometry | mass and
moles of substance
KEY: mole | mole
calculations
MSC: general chemistry
38. A
0.0103-mol sample of urea, NH2CONH2, contains
39. A) 02
´ 1023
molecules.
40. B) 48
´ 1022
molecules.
41. C) 96
´ 1022
atoms.
42. D) 48
´ 1023
atoms.
43. E) 03
´ 1024
atoms.
ANS:
C
PTS:
1
DIF:
easy
REF: 3.2
OBJ: Calculate the number of
molecules in a given mass of substance. (Example 3.6)
TOP: stoichiometry | mass and
moles of substance
KEY: mole | mole
calculations
MSC: general chemistry
39. How
many molecules are there in 90.0 g of butylene glycol, HO(CH2)4OH?
40. A) 1
41. B)
(6.02 ´
1023)/90.0
42. C) 0
43. D) 0 ´ (6.02 ´ 1023)
44. E) 02
´ 1023
ANS:
E
PTS:
1
DIF:
easy
REF: 3.2
OBJ: Calculate the number of
molecules in a given mass of substance. (Example 3.6)
TOP: stoichiometry | mass and
moles of substance
KEY: mole | mole
calculations
MSC: general chemistry
40. How
many molecules are there in 192 g of citric acid, C6H8O7?
41. A)
(6.02 ´
1023) / 192
42. B)
192
43. C) 02
´ 1023
44. D) 0
45. E)
192 ´
(6.02 ´
1023)
ANS:
C
PTS:
1
DIF:
easy
REF: 3.2
OBJ: Calculate the number of
molecules in a given mass of substance. (Example 3.6)
TOP: stoichiometry | mass and
moles of substance
KEY: mole | mole
calculations
MSC: general chemistry
41. In
0.358 mol of trimellitic acid, C6H3(COOH)3, there are
42. A) 16
´ 1022
molecules.
43. B) 62
´ 1024
molecules.
44. C) 47
´ 1023
oxygen atoms.
45. D) 94
´ 1024
carbon atoms.
46. E) 59
´ 1023
hydrogen atoms.
ANS:
D
PTS:
1
DIF:
moderate
REF: 3.2
OBJ: Calculate the number of
molecules in a given mass of substance. (Example 3.6)
TOP: stoichiometry | mass and moles
of substance
KEY: mole | mole
calculations
MSC: general chemistry
42. How
many molecules are there in 2.80 kg of hydrazine, N2H4?
43. A) 75
´ 1023
44. B) 27
´ 1025
45. C) 88
´ 1022
46. D) 80
´ 1026
47. E) 65
´ 1021
ANS:
B
PTS:
1
DIF:
moderate
REF: 3.2
OBJ: Calculate the number of
molecules in a given mass of substance. (Example 3.6)
TOP: stoichiometry | mass and
moles of substance
KEY: mole | mole
calculations
MSC: general chemistry
43. How
many molecules are there in 2.43 mg of mannose, C6H12O6, which is a
sweet-tasting sugar that has a bitter aftertaste?
44. A) 46
´ 1021
45. B) 48
´ 1021
46. C) 31
´ 1018
47. D) 04
´ 1024
48. E) 13
´ 1018
ANS: E
PTS:
1
DIF: moderate
REF: 3.2
OBJ: Calculate the number of
molecules in a given mass of substance. (Example 3.6)
TOP: stoichiometry | mass and
moles of substance
KEY: mole | mole calculations
MSC: general chemistry
44. How
many atoms are present in 463 g of KPF6 (MM = 184.1 g/mol)?
45. A) 23
´ 1025
46. B) 51
´ 1021
47. C) 51
´ 1021
48. D) 13
´ 1026
49. E) 21
´ 1025
ANS:
E
PTS:
1
DIF: moderate
REF: 3.2
OBJ: Calculate the number of
molecules in a given mass of substance. (Example 3.6)
TOP: stoichiometry | mass and
moles of substance
KEY: mole | mole
calculations
MSC: general chemistry
45. Styrene’s
empirical formula is CH. When it is heated to 200°C, it is converted into a
polymer, polystyrene, which has excellent insulating properties. What mass of
styrene contains 9.75 ´ 1021
molecules of styrene? The molar mass of styrene is 104 g/mol.
46. A)
0162 g
47. B) 68
g
48. C) 24
g
49. D)
210 g
50. E)
130 g
ANS:
B
PTS:
1
DIF: difficult
REF: 3.2
OBJ: Calculate the number of
molecules in a given mass of substance. (Example 3.6)
TOP: stoichiometry | mass and
moles of substance
KEY: mole | mole
calculations
MSC: general chemistry
46. In
0.500 mol of dimethylhydrazine, (CH3)2N2H2, there are
47. A) 01
´ 1024
molecules.
48. B) 51
´ 1023
atoms.
49. C) 01
´ 1022
molecules.
50. D) 61
´ 1024
atoms.
51. E) 81
´ 1024
atoms.
ANS:
D
PTS:
1
DIF:
moderate
REF: 3.2
OBJ: Calculate the number of
molecules in a given mass of substance. (Example 3.6)
TOP: stoichiometry | mass and moles
of substance
KEY: mole | mole
calculations
MSC: general chemistry
47. Which
is a reasonable mass corresponding to 1020 molecules of a substance?
48. A)
100 g
49. B)
100 µg
50. C)
100 ng
51. D)
100 mg
52. E)
100 kg
ANS:
D
PTS:
1
DIF:
moderate
REF: 3.2
OBJ: Calculate the number of
molecules in a given mass of substance. (Example 3.6)
TOP: stoichiometry | mass and
moles of substance
KEY: mole | mole
calculations
MSC: general chemistry
48. How
many aluminum atoms are there in 52 g of Al2S3?
49. A) 2 ´ 1023
50. B) 6 ´ 1021
51. C) 1 ´ 1023
52. D) 1 ´ 1021
53. E) 3 ´ 1023
ANS:
A
PTS:
1
DIF:
moderate
REF: 3.2
OBJ: Calculate the number of
molecules in a given mass of substance. (Example 3.6)
TOP: stoichiometry | mass and
moles of substance
KEY: mole | mole
calculations
MSC: general chemistry
49. Which
one of the following contains 2.41 ´ 1024
atoms?
50. A) 0
g C2H2
51. B) 0
g O2
52. C) 0
g CH4
53. D)
168 g N2
54. E) 0
g He
ANS:
E
PTS:
1
DIF:
moderate
REF: 3.2
OBJ: Calculate the number of
molecules in a given mass of substance. (Example 3.6)
TOP: stoichiometry | mass and
moles of substance
KEY: mole | mole
calculations
MSC: general chemistry
50. A
sample of 496 g of white phosphorus, P4, contains the same number of atoms as
51. A)
192 g of ozone (O3).
52. B) 0
g of nitrogen (N2).
53. C) 0
g of sodium.
54. D)
120 g of formaldehyde (CH2O).
55. E)
128 g of oxygen (O2).
ANS:
D
PTS:
1
DIF:
moderate
REF: 3.2
OBJ: Calculate the number of
molecules in a given mass of substance. (Example 3.6)
TOP: stoichiometry | mass and
moles of substance
KEY: mole | mole
calculations
MSC: general chemistry
51. The
total number of oxygen atoms in 1.76 g of CaCO3 (MM = 100.0 g/mol) is
52. A) 05
´ 1023.
53. B) 24
´
1022.
54. C) 18
´
1022.
55. D) 75
´
1023.
56. E) 30
´
1022.
ANS:
C
PTS:
1
DIF:
moderate
REF: 3.2
OBJ: Calculate the number of
molecules in a given mass of substance. (Example 3.6)
TOP: stoichiometry | mass and
moles of substance
KEY: mole | mole
calculations
MSC: general chemistry
52. A
sample of 336 g of ozone, O3, contains the same number of atoms as
53. A)
336 g of oxygen (O2).
54. B) 2
g of hydrogen (H2).
55. C) 266
g of fluorine (F2).
56. D)
189 g of aluminum (Al).
57. E)
411 g of nickel (Ni).
ANS:
A
PTS:
1
DIF:
moderate
REF: 3.2
OBJ: Calculate the number of
molecules in a given mass of substance. (Example 3.6)
TOP: stoichiometry | mass and
moles of substance
KEY: mole | mole
calculations
MSC: general chemistry
53. Which
of the following samples contains the smallest number of molecules?
54. A) 00
g of TNT, C7H5N3O6
55. B) 00
g of benzene, C6H6
56. C) 00
g of glucose, C6H12O6
57. D) 00
g of naphthalene, C10H8
58. E) 00
g of formaldehyde, CH2O
ANS:
A
PTS:
1
DIF:
moderate
REF: 3.2
OBJ: Calculate the number of
molecules in a given mass of substance. (Example 3.6)
TOP: stoichiometry | mass and
moles of substance
KEY: mole | mole
calculations
MSC: general chemistry
54. Which
of the following samples contains the largest number of atoms?
55. A) 1
g N2
56. B) 1
g Li
57. C) 1
g Cl2
58. D) 1
g P4
59. E) 1
g Mg
ANS:
B
PTS:
1
DIF:
moderate
REF: 3.2
OBJ: Calculate the number of
molecules in a given mass of substance. (Example 3.6)
TOP: stoichiometry | mass and
moles of substance
KEY: mole | mole
calculations
MSC: general chemistry
55. Which
of the following samples contains the largest number of molecules?
56. A) g
Pb
57. B) g
Cl2
58. C) g
Kr
59. D) g
O2
60. E) g
S8
ANS: D
PTS:
1
DIF: moderate
REF: 3.2
OBJ: Calculate the number of
molecules in a given mass of substance. (Example 3.6)
TOP: stoichiometry | mass and
moles of substance
KEY: mole | mole calculations
MSC: general chemistry
56. In
1928, 1.0 g of rhenium, Re, was isolated from 660 kg of the ore molybenite. The
percent by mass of this element in the molybenite was
57. A) 66
%.
58. B) 15
%.
59. C) 5 ´ 10–4 %.
60. D) 6 ´ 10–3 %.
61. E) 5 ´ 10–4 %.
ANS:
E
PTS:
1
DIF:
easy
REF: 3.3
OBJ: Calculate the
percentage composition of the elements in a compound. (Example 3.7)
TOP: stoichiometry | determining
chemical formulas KEY: mass percentage
MSC: general chemistry
57. An
ore sample is found to contain 24.1 g of mercury and 50.7 g waste rock
(gangue). What is the percent by mass of mercury in the ore?
58. A) 2
%
59. B) 4
%
60. C)
322 %
61. D)
474 %
62. E) 74
%
ANS:
A
PTS: 1
DIF:
easy
REF: 3.3
OBJ: Calculate the
percentage composition of the elements in a compound. (Example 3.7)
TOP: stoichiometry | determining
chemical formulas
58. An
ore sample with a mass of 68.0 g is found to contain 15.5% by mass
nickel. What mass of nickel is contained in the ore?
59. A) 5
g
60. B) 7
g
61. C) 55
g
62. D) 5
g
63. E)
546 g
ANS:
A
PTS:
1
DIF:
easy
REF: 3.3
OBJ: Calculate the
percentage composition of the elements in a compound. (Example 3.7)
TOP: stoichiometry | determining
chemical formulas
59. What
is the percent by mass oxygen in (NH4)2SO3?
60. A) 3
%
61. B) 7
%
62. C) 0
%
63. D) 0
%
64. E) 00
%
ANS:
A
PTS:
1
DIF:
easy
REF: 3.3
OBJ: Calculate the
percentage composition of the elements in a compound. (Example 3.7)
TOP: stoichiometry | determining
chemical formulas
60. What
is the percentage by mass of hydrogen in the insecticide Lindane, C6H6Cl6?
61. A) 0
%
62. B) 20
%
63. C) 2
%
64. D) 80
%
65. E) 08
%
ANS:
E
PTS:
1
DIF:
easy
REF: 3.3
OBJ: Calculate the
percentage composition of the elements in a compound. (Example 3.7)
TOP: stoichiometry | determining
chemical formulas
61. The
mineral leadhillite, which is essentially Pb4(SO4)(CO3)2(OH)2 (FW = 1079
g/mol), contains ____% hydrogen by mass.
62. A) 81
63. B)
1868
64. C)
226
65. D) 79
66. E)
972
ANS:
B
PTS: 1
DIF:
easy
REF: 3.3
OBJ: Calculate the
percentage composition of the elements in a compound. (Example 3.7)
TOP: stoichiometry | determining
chemical formulas KEY: mass percentage
MSC: general chemistry
62. Which
of the following compounds has the highest percentage of hydrogen atoms by
mass?
63. A)
CH3COOH
64. B)
C2H5OH
65. C)
CH3OH
66. D)
H2CO3
67. E)
H2C2O4
ANS:
B
PTS:
1
DIF:
easy
REF: 3.3
OBJ: Calculate the percentage
composition of the elements in a compound. (Example 3.7)
TOP: stoichiometry | determining
chemical formulas KEY: mass percentage
MSC: general chemistry
63. Which
of the following compounds has the highest percentage of nitrogen by mass?
64. A)
(NH4)2SO3
65. B)
NaNO3
66. C)
N2Cl4
67. D)
NH4NO2
68. E)
HNO3
ANS:
D
PTS:
1
DIF:
easy
REF: 3.3
OBJ: Calculate the
percentage composition of the elements in a compound. (Example 3.7)
TOP: stoichiometry | determining
chemical formulas KEY: mass percentage
MSC: general chemistry
64. Which
of the following compounds has the same percentage of carbon and hydrogen by
mass as cyclohexane, C6H12?
65. A)
C6H14, hexane
66. B)
C5H10, pentene
67. C)
C6H10, cyclohexene
68. D)
C6H6, benzene
69. E)
C6H12O6, glucose
ANS:
B
PTS:
1
DIF:
easy
REF: 3.3
OBJ: Calculate the
percentage composition of the elements in a compound. (Example 3.7)
TOP: stoichiometry | determining
chemical formulas KEY: mass percentage
MSC: general chemistry
65. What
is the mass percentage of carbon in the compound C6H6O2?
66. A) 5
%
67. B) 9
%
68. C) 5
%
69. D) 1
%
70. E) 3
%
ANS:
C
PTS:
1
DIF:
easy
REF: 3.3
OBJ: Calculate the
percentage composition of the elements in a compound. (Example 3.7)
TOP: stoichiometry | determining
chemical formulas KEY: mass percentage
MSC: general chemistry
66. What
is the percentage by mass of hydrogen in ammonium phosphate, (NH4)3PO4?
67. A) 11
%
68. B) 06
%
69. C) 0
%
70. D) 0
%
71. E) 00
%
ANS:
A
PTS:
1
DIF:
easy
REF: 3.3
OBJ: Calculate the
percentage composition of the elements in a compound. (Example 3.7)
TOP: stoichiometry | determining
chemical formulas
67. A
crystal of the mineral troegerite, (UO2)3(AsO4)2 • 12H2O (FM = 1304 amu),
contains ____% arsenic by mass.
68. A) 4
69. B) 8
70. C) 0
71. D) 4
72. E) 5
ANS:
E
PTS:
1
DIF:
easy
REF: 3.3
OBJ: Calculate the
percentage composition of the elements in a compound. (Example 3.7)
TOP: stoichiometry | determining
chemical formulas KEY: mass percentage
MSC: general chemistry
68. How
many grams of hydrogen atoms are present in 18.4 g of water?
69. A) 1
g
70. B) 02
g
71. C) 06
g
72. D) 96
g
73. E) 3
g
ANS:
C
PTS:
1
DIF:
easy
REF: 3.3
OBJ: Calculate the mass of
an element in a given mass of compound. (Example 3.8)
TOP: stoichiometry | mass and
moles of substance
KEY: mole | mole
calculations
MSC: general chemistry
69. How
many grams of potassium are present in 21.6 g of K2Cr2O7?
70. A) 74
g
71. B)
105 g
72. C) 87
g
73. D) 2
g
74. E) 8
g
ANS:
A
PTS:
1
DIF:
moderate
REF: 3.3
OBJ: Calculate the mass of
an element in a given mass of compound. (Example 3.8)
TOP: stoichiometry | determining
chemical formulas KEY: mass percentage
MSC: general chemistry
70. NaHCO3
is the active ingredient in baking soda. How many grams of oxygen are present
in 0.67 g of NaHCO3?
71. A)
024 g
72. B)
128 g
73. C) 98
´ 103
g
74. D)
043 g
75. E) 38
g
ANS:
E
PTS:
1
DIF:
easy
REF: 3.3
OBJ: Calculate the mass of
an element in a given mass of compound. (Example 3.8)
TOP: stoichiometry | determining
chemical formulas KEY: mass percentage
MSC: general chemistry
71. Which
of the following contains the greatest mass of bromine atoms?
72. A) 0
g of KBr
73. B) 0
g of Br2
74. C)
076 mol of KBr
75. D)
092 mol of Br2
76. E) 0
g of NaBrO3
ANS:
B
PTS:
1
DIF:
moderate
REF: 3.3
OBJ: Calculate the mass of
an element in a given mass of compound. (Example 3.8)
TOP: stoichiometry | determining
chemical formulas KEY: mass percentage
MSC: general chemistry
72. The
amount of calcium in a 15.0-g sample was determined by converting the calcium
to calcium oxalate, CaC2O4. The CaC2O4 weighed 12.6 g. What is the
percent of calcium in the original sample?
73. A) 8
%
74. B) 3
%
75. C) 8
%
76. D) 7
%
77. E) 0
%
ANS: B
PTS:
1
DIF: difficult REF:
3.3
OBJ: Calculate the mass of
an element in a given mass of compound. (Example 3.8)
TOP: stoichiometry | mass and
moles of substance
KEY: mole | mole
calculations
MSC: general chemistry
73. A
compound containing only carbon, hydrogen, and oxygen is subjected to elemental
analysis. Upon complete combustion, a 0.1804-g sample of the compound
produced 0.3051 g of CO2 and 0.1249 g of H2O. What is the empirical
formula of the compound?
74. A)
C3H6O3
75. B)
C3H3O
76. C)
C4H8O3
77. D)
C2H2O
78. E)
CH2O3
ANS:
C
PTS:
1
DIF:
moderate
REF: 3.4
OBJ: Calculate the
percentage of C, H, and O from combustion data. (Example 3.9)
TOP: stoichiometry | determining
chemical formulas KEY: elemental analysis
MSC: general chemistry
74. A
3.075 g sample of a compound containing only carbon, hydrogen, and oxygen is
burned in an excess of dioxygen, producing 6.990 g CO2 and 2.862 g H2O.
What mass of oxygen is contained in the original sample?
75. A)
8472 g
76. B)
167 g
77. C)
915 g
78. D)
129 g
79. E)
2134 g
ANS:
A
PTS:
1
DIF:
moderate
REF: 3.4
OBJ: Calculate the percentage
of C, H, and O from combustion data. (Example 3.9)
TOP: stoichiometry | determining
chemical formulas
75. A
4.043 g sample of a compound containing only carbon, hydrogen, and oxygen is
burned in an excess of dioxygen, producing 9.191 g CO2 and 3.762 g H2O.
What percent by mass of oxygen is contained in the original sample?
76. A) 54
%
77. B) 96
%
78. C) 73
%
79. D) 43
%
80. E)
939 %
ANS:
A
PTS:
1
DIF:
moderate
REF: 3.4
OBJ: Calculate the percentage
of C, H, and O from combustion data.
TOP: stoichiometry | determining
chemical formulas
76. A
2.841 g sample of a hydrocarbon is burned in an excess of dioxygen, producing
7.794 g CO2 and water. What mass of hydrogen is contained in the original
sample?
77. A)
7140 g
78. B)
953 g
79. C) 64
g
80. D)
826 g
81. E)
421 g
ANS:
A
PTS:
1
DIF:
moderate
REF: 3.4
OBJ: Calculate the
percentage of C, H, and O from combustion data. (Example 3.9)
TOP: stoichiometry | determining
chemical formulas
77. A
2.445 g sample of a hydrocarbon is burned in an excess of dioxygen, producing
6.708 g CO2 and 5.492 g H2O. What is the empirical formula of the
hydrocarbon?
78. A)
CH4
79. B)
CH2
80. C)
C2H3
81. D)
CH3
82. E) CH
ANS:
A
PTS:
1
DIF:
moderate
REF: 3.5
OBJ: Determine the empirical
formula of a binary compound.
TOP: stoichiometry | determining
chemical formulas
78. A
0.4647-g sample of a compound known to contain only carbon, hydrogen, and
oxygen was burned in dioxygen to yield 0.01962 mol of CO2 and 0.01961 mol of
H2O. What is the empirical formula of the compound?
79. A)
CHO
80. B)
C3H3O2
81. C)
C2H2O
82. D)
C3H6O2
83. E)
C6H3O2
ANS:
D
PTS:
1
DIF:
moderate
REF: 3.4
OBJ: Calculate the
percentage of C, H, and O from combustion data. (Example 3.9)
TOP: stoichiometry | determining
chemical formulas
79. A
sample containing only carbon, hydrogen, phosphorus, and oxygen is subjected to
elemental analysis. After complete combustion, a 0.4946-g sample of the
compound yields 0.7092 g of CO2, 0.4355 g of H2O, and 0.3812 g of P4O10.
What is the empirical formula of the compound?
80. A)
CH3PO
81. B)
C2H3PO
82. C)
C2H6P2O4
83. D)
C3H9PO
84. E)
CH2P4O13
ANS:
D
PTS:
1
DIF: difficult
REF: 3.4
OBJ: Calculate the
percentage of C, H, and O from combustion data. (Example 3.9)
TOP: stoichiometry | determining chemical
formulas KEY: elemental analysis
MSC: general chemistry
80. A
sample containing only carbon, hydrogen, and silicon is subjected to elemental
analysis. After complete combustion, a 0.1099-g sample of the compound
yields 0.2193 g of CO2, 0.1346 g of H2O, and 0.07485 g of SiO2. What is
the empirical formula of the compound?
81. A)
CH3Si
82. B)
C2H4Si
83. C)
C4H12Si
84. D)
C6H12Si2
85. E)
CH2Si
ANS:
C
PTS:
1
DIF: difficult
REF: 3.4
OBJ: Calculate the percentage
of C, H, and O from combustion data. (Example 3.9)
TOP: stoichiometry | determining
chemical formulas KEY: elemental analysis
MSC: general chemistry
81. Of
the following, the only empirical formula is
82. A)
83. B)
84. C)
85. D)
86. E)
ANS:
C
PTS:
1
DIF:
easy
REF: 3.5
OBJ: Define empirical
formula.
TOP: stoichiometry | determining
chemical formulas KEY: empirical formula
MSC: general chemistry
82. Which
of the following is the empirical formula for the molecule below?
1. A)
CHO
2. B)
CH3COOH
3. C)
C2H4O2
4. D)
CH2O
5. E)
none of the above.
ANS:
D
PTS:
1
DIF:
easy
REF: 3.5
OBJ: Define empirical
formula.
TOP: stoichiometry | determining
chemical formulas KEY: empirical formula
MSC: general chemistry
83. Analysis
of a compound showed that it contained 76.0 % fluorine atoms and 24.0 % carbon
atoms by mass. What is its empirical formula?
84. A)
CF2
85. B)
C2F3
86. C)
CF3
87. D)
C2F5
88. E) CF
ANS:
A
PTS:
1
DIF:
moderate
REF: 3.5
OBJ: Determine the empirical
formula of a binary compound from the masses of its elements. (Example 3.10)
TOP: stoichiometry | determining
chemical formulas KEY: empirical formula
MSC: general chemistry
84. A
sample of an oxide of antimony (Sb) contained 39.5 g of antimony combined with
13.0 g of oxygen. What is the simplest formula for the oxide?
85. A)
SbO2
86. B) SbO
87. C)
Sb2O3
88. D)
Sb2O
89. E)
Sb2O5
ANS:
E
PTS:
1
DIF:
moderate
REF: 3.5
OBJ: Determine the empirical
formula of a binary compound from the masses of its elements. (Example 3.10)
TOP: stoichiometry | determining
chemical formulas KEY: empirical formula
MSC: general chemistry
85. Chlorine
was passed over 1.30 g of heated titanium, and 4.20 g of a chloride-containing
compound of Ti was obtained. What is the empirical formula of the chloride-containing
compound?
86. A)
TiCl2
87. B)
TiCl4
88. C)
TiCl
89. D)
TiCl3
90. E)
Ti2Cl3
ANS:
D
PTS:
1
DIF:
moderate
REF: 3.5
OBJ: Determine the empirical
formula of a binary compound from the masses of its elements. (Example 3.10)
TOP: stoichiometry | determining
chemical formulas KEY: empirical formula
MSC: general chemistry
86. A
2.39-g sample of an oxide of chromium contains 1.48 g of chromium. Calculate
the simplest formula for the compound.
87. A)
CrO5
88. B)
Cr2O
89. C)
CrO2
90. D)
CrO
91. E)
Cr2O3
ANS:
C
PTS:
1
DIF:
moderate
REF: 3.5
OBJ: Determine the empirical
formula of a binary compound from the masses of its elements. (Example 3.10)
TOP: stoichiometry | determining
chemical formulas KEY: empirical formula
MSC: general chemistry
87. A
compound is composed of only C and H. It contains 92.26 % C. What is its
empirical formula?
88. A)
C2H5
89. B)
C2H3
90. C)
C3H4
91. D) CH
92. E) CH2
ANS:
D
PTS:
1
DIF:
easy
REF: 3.5
OBJ: Determine the empirical
formula from the percentage composition. (Example 3.11)
TOP: stoichiometry | determining
chemical formulas KEY: empirical formula
MSC: general chemistry
88. A
compound composed of only C and F contains 17.39 % C by mass. What is its
empirical formula?
89. A)
CF3
90. B) CF
91. C)
C2F
92. D)
CF4
93. E)
CF2
ANS:
A
PTS:
1
DIF:
easy REF:
3.5
OBJ: Determine the empirical
formula from the percentage composition. (Example 3.11)
TOP: stoichiometry | determining
chemical formulas KEY: empirical formula
MSC: general chemistry
89. A
hydrocarbon, subjected to elemental analysis, was found to contain 85.63 %
carbon and 14.37 % hydrogen by mass. What is the empirical formula of the
hydrocarbon?
90. A)
CH4
91. B)
C2H4
92. C)
C6H
93. D)
C10H
94. E)
CH2
ANS:
E
PTS:
1
DIF:
easy REF:
3.5
OBJ: Determine the empirical
formula from the percentage composition. (Example 3.11)
TOP: stoichiometry | determining
chemical formulas KEY: empirical formula
MSC: general chemistry
90. A
particular compound contains, by mass, 41.4 % carbon, 3.47 % hydrogen, and 55.1
% oxygen. A 0.050-mol sample of this compound weighs 5.80 g. The
molecular formula of this compound is
91. A)
92. B)
93. C)
94. D)
95. E)
ANS:
D
PTS:
1
DIF: moderate
REF: 3.5
OBJ: Determine the empirical
formula from the percentage composition. (Example 3.11)
TOP: stoichiometry | determining
chemical formulas
KEY: molecular
formula
MSC: general chemistry
91. What
is the empirical formula of an oxide of nitrogen that contains 25.93 % nitrogen
by mass?
92. A)
NO2
93. B)
N2O
94. C)
N2O3
95. D) NO
96. E)
N2O5
ANS:
E
PTS:
1
DIF:
moderate
REF: 3.5
OBJ: Determine the empirical
formula from the percentage composition. (Example 3.11)
TOP: stoichiometry | determining
chemical formulas KEY: empirical formula
MSC: general chemistry
92. The
analysis of an organic compound showed that it contained 1.386 mol of C, 0.0660
mol of H, 0.924 mol of O, and 0.462 mol of N. How many nitrogen atoms are there
in the empirical formula for this compound?
93. A) 9
94. B) 7
95. C) 2
96. D) 4
97. E) 3
ANS:
B
PTS:
1
DIF:
easy REF:
3.5
OBJ: Determine the empirical
formula from the percentage composition. (Example 3.11)
TOP: stoichiometry | determining
chemical formulas KEY: empirical formula
MSC: general chemistry
93. A
sample containing 0.700 mol of a compound is composed of 4.21 ´ 1023 atoms of sodium,
24.79 g of chlorine atoms, and 33.57 g of oxygen atoms. The formula of the
compound is
94. A)
95. B)
96. C)
97. D)
98. E)
ANS:
A
PTS:
1
DIF:
moderate
REF: 3.5
OBJ: Determine the empirical
formula from the percentage composition. (Example 3.11)
TOP: stoichiometry | determining
chemical formulas KEY: empirical formula
MSC: general chemistry
94. The
analysis of an organic compound showed that it contained 0.0700 mol of C, 0.175
mol of H, and 0.0350 mol of N. Its molecular mass is 86 amu. How many atoms of
carbon are there in the empirical formula for the compound, and how many are in
the molecular formula?
95. A)
empirical = 2, molecular = 3
96. B)
empirical = 2, molecular = 6
97. C)
empirical = 2, molecular = 4
98. D)
empirical = 5, molecular = 10
99. E)
empirical = 3, molecular = 3
ANS:
C
PTS:
1
DIF:
moderate
REF: 3.5
OBJ: Determine the empirical
formula from the percentage composition. (Example 3.11)
TOP: stoichiometry | determining
chemical formulas
KEY: molecular
formula
MSC: general chemistry
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