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Sample Test

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53
Chapter 3, Problem 1
Define the following terms: (a) crystalline solid, (b) long-range order, (c) short-range order, and
(d) amorphous.
Chapter 3, Solution 1
(a) a solid that has an organized, repeating, 3D positioning of atoms or ions in its structure;
(b) the positioning of atoms is periodic and repeating anywhere in the crystal. All atoms have the same
geometric environment; (c) there is some order (organized positioning of atoms), but it is local or limited to
certain regions of the material; (d) there is no organized positioning of atoms. All atom positions in the
structure are random.
Chapter 3, Problem 2
Define the following terms: (a) crystal structure. (b) space lattice, (c) lattice point, (d) unit cell, (e) motif, and
(f) lattice constants
Chapter 3, Solution 2
(a) a regular, 3D pattern of atoms or ions in space; (b) a three-dimensional array of points each of
which has the same geometric environment; (c) one point in the array in a space lattice;
(d) the smallest, repeating unit of a space lattice; (e) a group of atoms that are organized relative to
each other and are associated with a lattice point; (f) length dimensions or angles that characterize
the geometry of a unit cell.
Chapter 3, Problem 3
What are the 14 Bravais unit cells?
Chapter 3, Solution 3
The fourteen Bravais lattices are: simple cubic, body-centered cubic, face-centered cubic, simple
tetragonal, body-centered tetragonal, simple orthorhombic, base-centered orthorhombic, body-centered
orthorhombic, face-centered orthorhombic, simple rhombohedral, simple hexagonal, simple monoclinic,
base-centered monoclinic, and simple triclinic.
Chapter 3, Problem 4
What are the three most common metal crystal structures? List five metals that have each of these crystal
structures.
Chapter 3, Solution 4
The three most common crystal structures found in metals are: body-centered cubic (BCC), face-centered
cubic (FCC), and hexagonal close-packed (HCP). Examples of metals having these structures include the
following.
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BCC: a-iron, vanadium, tungsten, niobium, and chromium.
FCC: copper, aluminum, lead, nickel, and silver.
HCP: magnesium, a-titanium, zinc, beryllium, and cadmium.
Chapter 3, Problem 5
For a BBC unit cell, (a) how many atoms are there inside the unit cell, (b) what is the coordination number
for the atoms, (c) what is the relationship between the length of the side a of the BCC unit cell and the
radius of its atoms, and (d) what is the atomic packing factor? APF = 0.68 or 68%
Chapter 3, Solution 5
(a) A BCC crystal structure has two atoms in each unit cell. (b) A BCC crystal structure has a coordination
number of eight. (c) In a BCC unit cell, one complete atom and two atom eighths touch each other along
the cube diagonal. This geometry translates into the relationship 3a = 4R. (d) the atomic packing
factor is:
volume of atoms in FCC unit cell
Atomic packing factor
volume of the FCC unit cell
=
3
Vunit cell =a
The volume of atoms associated with this unit cell is the number of atoms in the unit cell multiplied by the
volume of each atom
3
4 3 4 3
2 2
3 3 4 atoms
a
V pR p
é ù é æ ö ù ê ú ê çç ÷÷ ú = ê ú = ê ç ÷÷ ú ë û ê çè ÷ø ú êë úû
Therefore, the APF for BCC is:
3
3
4 3
2
3 4
0.68
a
APF
a
p
é æ ö ù ê çç ÷÷ ú ê ç ÷÷ ú ê çè ÷ø ú = êë úû =
Chapter 3, Problem 6
For an FCC unit cell, (a) how many atoms are there inside the unit cell, (b) What is the coordination number
for the atoms, (c) what is the relationship between the length of side a of the FCC unit cell and the radius of
its atom, and (d) what is the atomic packing factor?
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Chapter 3, Solution 6
(a) Each unit cell of the FCC crystal structure contains four atoms. (b) The FCC crystal structure has a
coordination number of twelve. (c) the geometry can be used to find the relationship of
4
2
R
a =
(d) By definition, the atomic packing factor is given as:
volume of atoms in FCC unit cell
Atomic packing factor
volume of the FCC unit cell
=
These volumes, associated with the four-atom FCC unit cell, are
4 3 16 3
4
3 3 Vatoms pR pR
é ù
= ê ú = êë úû
and 3
Vunit cell =a
where a represents the lattice constant. Substituting
4
2
R
a = ,
3
3
unit cell
64
2 2
R
V =a =
The atomic packing factor then becomes,
3
3
16 1 2 2
APF (FCC unit cell)
3 32 6
R
R
=æçç p ÷÷öæçç ÷÷ö= p çç ÷÷÷çç ÷÷÷ è øè ø
= 0.74
Chapter 3, Problem 7
For an HCP unit cell (consider the primitive cell), (a) how many atoms are there inside the unit cell, (b) What
is the coordination number for the atoms, (c) what is the atomic packing factor, (d) what is the ideal c/a ratio
for HCP metals, and (e) repeat (a) through (c) considering the “larger” cell.
Chapter 3, Solution 7
The primitive cell has (a) two atoms/unit cell; (b) The coordination number associated with the HCP crystal
structure is twelve. (c) the APF is 0.74 or 74%; (d) The ideal c/a ratio for HCP metals is 1.633; (e) all answers
remain the same except for (a) where the new answer is 6.
Chapter 3, Problem 8
How are atomic positions located in cubic unit cells?
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Chapter 3, Solution 8
Atomic positions are located in cubic unit cells using rectangular x, y, and z axes and unit distances along
the respective axes. The directions of these axes are shown below.
Chapter 3, Problem 9
List the atom positions for the eight corner and six face-centered atoms of the FCC unit cell.
Chapter 3, Solution 9
The atom positions at the corners of an FCC unit cell are:
(0, 0, 0), (1, 0, 0), ( 1, 1, 0), (0, 1, 0), (0, 0, 1), (1, 0, 1), (1, 1, 1), (0, 1, 1)
On the faces of the FCC unit cell, atoms are located at:
(½, ½, 0), (½, 0, ½), (0, ½, ½), (½, ½, 1), (1, ½, ½), (½, 1, ½)
Chapter 3, Problem 10
How are the indices for a crystallographic direction in a cubic unit cell determined?
Chapter 3, Solution 10
For cubic crystals, the crystallographic direction indices are the components of the direction vector,
resolved along each of the coordinate axes and reduced to the smallest integers. These indices are
designated as [uvw].
Chapter 3, Problem 11
What are the crystallographic directions of a family or form? What generalized notation is used to indicate
them?
Chapter 3, Solution 11
A family or form has equivalent crystallographic directions; the atom spacing along each direction is
identical. These directions are indicated by uvw .
+z
−z
−x
−y
+x
y
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Chapter 3, Problem 12
How are the Miller indices for a crystallographic plane in a cubic unit cell determined? What generalized
notation is used to indicate them?
Chapter 3, Solution 12
The Miller indices are determined by first identifying the fractional intercepts which the plane makes with
the crystallographic x, y, and z axes of the cubic unit cell. Then, all fractions must be cleared such that the
smallest set of whole numbers is attained. The general notation used to indicate these indices is (hkl),
where h, k, and l correspond to the x, y and z axes, respectively.
Chapter 3, Problem 13
What is the notation used to indicate a family or form of cubic crystallographic planes?
Chapter 3, Solution 13
A family or form of a cubic crystallographic plane is indicated using the notation {hkl}.
Chapter 3, Problem 14
How are crystallographic planes indicated in HCP unit cells?
Chapter 3, Solution 14
In HCP unit cells, crystallographic planes are indicated using four indices which correspond to four axes:
three basal axes of the unit cell, a1, a2, and a3 , which are separated by 120º; and the vertical c axis.
Chapter 3, Problem 15
What notation is used to describe HCP crystal planes?
Chapter 3, Solution 15
HCP crystal planes are described using the Miller-Bravais indices, (hkl).
Chapter 3, Problem 16
What is the difference in the stacking arrangement of close-packed planes in (a) the HCP crystal structure
and (b) the FCC crystal structure?
Chapter 3, Solution 16
Although the FCC and HCP are both close-packed lattices with APF = 0.74, the structures differ in the
three dimensional stacking of their planes:
(a) the stacking order of HCP planes is ABAB… ;
(b) the FCC planes have an ABCABC… stacking sequence.
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Chapter 3, Problem 17
What are the closest-packed directions in (a) the BCC structure, (b) the FCC structure and (c) the HCP
structure?
Chapter 3, Solution 17
(a) The closest packed directions in BCC lattice are < 1 1 1 > directions.
(b) The closest-packed directions in the FCC lattice are the 1 10 directions.
(c) The closest-packed directions in the HCP lattice are the 1120 directions.
Chapter 3, Problem 18
Identify the close-packed planes in (a) the BCC structure, (b) the FCC structure, and (c) the HCP structure.
Chapter 3, Solution 18
(a) Does not have a close-packed plane; (b) {111} planes; (c) {0001} planes
Chapter 3, Problem 19
What is polymorphism with respect to metals?
Chapter 3, Solution 19
A metal is considered polymorphic if it can exist in more than one crystalline form under different
conditions of temperature and pressure.
Chapter 3, Problem 20
What are X rays, and how are they produced?
Chapter 3, Solution 20
X-rays are electromagnetic radiation having wavelengths in the range of approximately 0.05 nm to
0.25 nm. These waves are produced when accelerated electrons strike a target metal.
Chapter 3, Problem 21
Draw a schematic diagram of an x-ray tube used for x-ray diffraction, and indicate on it the path of the
electrons and X rays.
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Chapter 3, Solution 21
See Figure 3.25 of textbook.
Figure 3.25
Chapter 3, Problem 22
What is the characteristic x-ray radiation? What is its origin?
Chapter 3, Solution 22
Characteristic radiation is an intense form of x-ray radiation which occurs at specific wavelengths for a
particular element. The Ka radiation, the most intense characteristic radiation emitted, is caused by excited
electrons dropping from the second atomic shell
(n = 2) to the first shell (n = 1). The next most intense radiation, Kb, is caused by excited electrons dropping
from the third atomic shell (n = 3) to the first shell (n = 1).
Chapter 3, Problem 23
Distinguish between destructive interference and constructive interference of reflected x-ray beams
through crystals.
Chapter 3, Solution 23
Destructive interference occurs when the wave patterns of x-ray beams, reflected from a crystal, are out of
phase. Conversely, when the wave patterns leaving a crystal plane are in phase, constructive interference
occurs and the beam is reinforced.
Copper X rays Vacuum
Electrons
Cooling water
Target
Beryllium window X rays Metal focusing cup
To transformer
Tungsten
filament lass
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Application and Analysis Problems
Chapter 3, Problem 24
Tungsten at 20
°C is BCC and has an atomic radius of 0.137 nm. Calculate a value for its lattice constant
a in nanometers. (b) Calculate the volume of the unit cell.
Chapter 3, Solution 24
Letting a represent the edge length of the BCC unit cell and R the tungsten atomic radius,
4 4 ( )
3 4 or 0.137nm
3 3
a = R a = R = = 0.316 nm
Since BCC has a cubic structure, the length of each side is a. Therefore its volume should be
V = a3 = 0.316nm3 = 0.0316 nm3
Chapter 3, Problem 25
Lead is FCC and has an atomic radius of 0.175 nm. (a) Calculate a value for its lattice constant
a in nanometers. (b) Calculate the volume of the unit cell in nm3 .
Chapter 3, Solution 25
Letting a represent the FCC unit cell edge length and R the palladium atomic radius,
4 4 ( )
2 2
2a = 4R or a = R = 0.175 nm = 0.495 nm
Since FCC has a cubic structure, the length of each side is a. Therefore its volume should be
V = a3 = 0.495nm3 = 0.121 nm3
Chapter 3, Problem 26
Verify that the atomic packing factor for the FCC structure is 0.74.
Chapter 3, Solution 26
By definition, the atomic packing factor is given as:
volume of atoms in FCC unit cell
Atomic packing factor
volume of the FCC unit cell
=
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These volumes, associated with the four-atom FCC unit cell, are
4 3 16 3
4
3 3 Vatoms pR pR
é ù
= ê ú = êë úû
and 3
Vunit cell = a
where a represents the lattice constant. Substituting
4
2
R
a = ,
3
3
unit cell
64
2 2
R
V = a =
The atomic packing factor then becomes,
3
3
16 1 2 2
APF (FCC unit cell)
3 32 6
R
R
=æçç p ÷÷öæçç ÷÷ö= p = çç ÷÷÷çç ÷÷÷ è øè ø
0.74
Chapter 3, Problem 27
Calculate the volume in cubic nanometers of the cobalt crystal structure unit cell (use the larger cell).
Cobalt is HCP at 20
°C with a = 0.2507 nm and c = 0.4069 nm.
Chapter 3, Solution 27
For a hexagonal prism, of height c and side length a, the volume is given by:
( )( ) ( )( )
( )( )
( )( )( )
o
o
2
2
3
Area of Base Height 6 Equilateral Triangle Area Height
3 sin60
3 0.2507 sin 60 0.4069
0.0664
V
a c
nm nm
nm
= = éê ´ ùú ë û
=
=
=
Chapter 3, Problem 28
Consider a 0.05-mm thick, 500 mm2 (about three times the area of a dime) piece of aluminum foil. How
many unit cells exist in the foil? If the density of aluminum is 2.7 g/cm3, what is the mass of each cell?
Chapter 3, Solution 28
A = 500mm2 t = 0.05mm
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Thickness = 0.05 mm Area = 500 mm2
a) The lattice constant for aluminum is a = 0.405nm
a = 0.405 nm = 0.405´10-6 mm
volume of the sheet = (A)(t) = (500)(0.05) = 25 mm3
volume of a single cell = a3 = ( 0.405´ 10-6 )3
Þ a3 =6.64´ 10-20 mm3
number of unit cell in the sheet
3
20 3
25 mm
6.64 10- mm =
´
number of cells = 3.76´ 1020 ( ~ 2000 times smaller than Avogadro’s number)
b)
m
V
r =
m = rV =
20 3 3 3
3 3
2.7 gr 6.64 10 mm 10 cm
cm mm
æçç ÷÷öççæ ´ – ´ – ÷÷ö çè ÷øçè ÷ø
m = 1.8 ´10-22 gr
Chapter 3, Problem 29 Draw the following directions in a BCC unit cell and list the position coordinates of
the atoms whose centers are intersected by the direction vector: Determine the repeat distance in terms of
the lattice constant in each direction.
(a) [010] (b) [011] (c) [111] (d) Find the angle between directions in (b) and (c)
Chapter 3, Solution 29
(a) Position Coordinates: (b) Position Coordinates: (c) Position Coordinates:
(0, 0, 0), (0, 1, 0) (0, 0, 0), (0, 1, 1) (0, 0, 0), (1, 1, 1),
The repeat distance is defined as the distance between two consecutive lattice points on
a specified direction
z
y
(0, 0, 0) (0, 0, 0)
(0, 0, 0)
(1, 1, 1)
(0,1,0)
(0,1,1)
x
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(a) repeat distance:
The distance between the centers of the atoms corner atoms is a, so repeat distance is a
(b) repeat distance:
The distance between the centers of the corner atoms is 2a, so the repeat distance is 2a
(c) repeat distance:
The distance between the center of the corner atom, and the center of the BCC center atom is
( 3 /2)a, so the repeat distance is ( 3/2)a
(d) the angle between two directions can be found using:
1 2 1 2 1 2
2 2 2 2 2 2
1 1 1 2 2 2
h h k k l l
cos
h k l h k l
q
+ +
=
+ + + +
q = 35.26 Degrees
Chapter 3, Problem 30
Draw direction vectors in an FCC unit cell for the following cubic directions, and list the position
coordinated of the atoms whose centers are intersected by the direction vector. Determine the repeat
distance in terms of the lattice constant in each direction
(a)é1 1 1ù (b)é10 1 ù (c)é21 1ù (d)é1 3 1ù (e)Find the angle between directions in(b)and(d).
êë úû êë úû êë úû êë úû
Chapter 3, Solution 30
z
x
y
a) (1 1 1)
c) (211)
b)
1/3
1/3
1/3
d) (131)
(1 0 1)
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64
Position coordinates
a) (0,0,0), (-1, -1, 1) b) (0,0,0) (1 ,0, -1) (1/2, 0, -1/2) c) (0,0,0,) (1, -1/2, -1/2) (2, -1, -1)
d) (0,0,0) (-1, 3, -1)
Repeat distances:
a) The distance between two lattice points (in this case, the corner atoms) is ( 3)a
b) The distance between two lattice points (in this case, the corner atom the face-centered atom)
is ( 2/2)a
c) The distance between two lattice points (in this case, the corner atom and the face-centered atom
is ( 3 / 2)a
d) The distance between two lattice points (in this case, the corner atom and the corner atom two lattice
cells over) is ( 11)a
e) The angle between (b) and (d) can be calculated using the following equation:
1 2 1 2 1 2
2 2 2 2 2 2
1 1 1 2 2 2
h h k k l l
cos
h k l h k l
q
+ +
=
+ + + +
q =64.76 Degrees
Chapter 3, Problem 31
Draw direction vectors in unit cells for the following cubic directions:
(a) éêë1 12ùúû (c) éêë331ùúû (e) éêë212ùúû (g) éêë 101ùúû (i) éë321ùû (k) éêë122ùúû
(b) éêë123ùúû (d) éêë021ùúû (f) éêë233ùúû (h) éêë121 ùúû (j) éêë103ùúû (l) éêë223ùúû
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65
Chapter 3, Solution 31
z
y
½ x




½
½
½
1
1
1
1
1
(a) Dividing
1
1
1
[ 1 1 2 ] by 2, (b) Dividing [ 123] by 3, (c) Dividing [331] by 3,
x = , 1
2
x = , 2
3
y = , 1
2
,
1
2
z = 1 z = 1
3
x = , x = 1, y =1, 1
3
y = , 2
3
z = 1
(d) Dividing [021] by 2, (e) Dividing [212] by 2, (f) Dividing [233] by 3,
z = 1
2
x =0 , y = 1, x =1, y = z= 1 y = 1, z= 1
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66
Figure P3.32
Chapter 3, Problem 32
What are the indices of the directions shown in the unit cubes of Fig. P3.32?
1 1
1
1
1 1
1
½
½
½





(g) For [101], (h) Dividing [ 1 2 1 ] by 2, (i) Dividing [321] by 3,
x = 1, y = 0, z =1 x =1,
z = 1 y= 1 z = 1
x = , , 1
2
y = , 2
3
z =1
3
z = 1
2
x= 2
3
y=1
x = , , 1
3
x , , , y= 2
3
= , 1
2
y=0 z=1
( j) Dividing [103] by 3, (k) Dividing [ 122] by 2, (l) Dividing [223] by 3,
z
a
e
h
f
g
c
b
1
3
y
x
(a)
z
y
x
(b)
d
3
4
1
2
1
2
1
4
1
4
1
4
1
4
3
4
3
4
2
3
1
3
1
2
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67
Chapter 3, Solution 32
a
b
c
½
a. Vector components:
Direction indices: [ 1 1 0 ]
x = −1, y = 1, z = 0
b. Moving direction vector c. Moving direction vector fordown
¼, vector components ward ½, vector components
are: x = 1, y = −1, z = are: x = − , y = 1, z = 1
½

1 6
1 6
New 0
New 0
¼
¼
¼Direction indices: [441] Direction indices: [166]
d e
f
½ ¼
¼



¼
d. Moving direction vector e. Vector components are: f. Moving direction vector up
left ¼, vector components ⅓, vector components are:
are: x = 1, y = ½, z = 1
x = −¾, y = −1, z = 1
x = −1, y = 1, z =−⅓
New 0
New 0
Direction indices: [212]

Direction indices: [344] Direction indices: [331]
x
z
y
z
y
a
¼
½ ¼
¾
½

b
c
d
(a) (b)
¼
¾
½

¼
¾

f
g
h
e
x
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68
Chapter 3, Problem 33
A direction vector passes through a unit cube from the
3 1
,0,
4 4
æç ÷öçç ÷÷÷ è ø
to the
1
, 1,0
2
æç ÷öçç ÷÷÷ è ø
positions. What are its
direction indices?
Chapter 3, Solution 33
The starting point coordinates, subtracted from the end point, give the vector components:
1 3 1 1 1
1 0 1 0
2 4 4 4 4
x = – =- y = – = z = – =-
The fractions can then be cleared through multiplication by 4, giving x =-1, y = 4, z =-1 . The direction
indices are therefore éêë 1 41ùúû .
Chapter 3, Problem 34
A direction vector passes through a unit cube from the
3
1,0,
4
æç ÷öçç ÷÷÷ è ø
to the
1 1
, 1,
4 4
æç ÷öçç ÷÷÷ è ø
positions. What are its
direction indices?
Chapter 3, Solution 34
Subtracting coordinates, the vector components are:
1 3 1 3 1
1 1 0 1
4 4 4 4 2
x = – =- y = – = z = – =-
¾
g.
h. Moving direction vector
up ¼, vector components
are: x = ¾, y = −1, z = −¾
Direction indices:
¾
−¾
¾
¼
½
New 0 New 0
g h
[441]
[343]
Moving direction vector
up ½, vector components
are: x = 1, y = −1, z = −¼
Direction indices:
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69
Clearing fractions through multiplication by 4, gives x =-3, y = 4, z =-2.
The direction indices are therefore éêë3 4 2ùúû .
Chapter 3, Problem 35
What are the directions of the á103ñ family or form for a unit cube? Draw all the directions in a unit cell.
Chapter 3, Solution 35
[ 103] , [301] , [310] , [130] , [031] , [013] , [103] , [130] , [310] , [301] , [031] , [013] , [ 103] , [3 10] , [ 130] ,
[301 ] , [0 13] , [031 ] , [ 103] , [3 10] , [ 1 30] , [301 ] , [031 ] , [0 1 3]
Chapter 3, Problem 36
What are the directions of the 111 family or form for a unit cube? Draw all the directions in a BCC unit cell.
Can you identify a special quality of these directions?
Chapter 3, Solution 36
[111] , [1 1 1] , [1 1 1] , [ 1 1 1] ,
[ 1 11] , [1 1 1] , [11 1] , [ 1 1 1]
These directions intersect in the middle of the cube.
[111]
[111]
[111]
[111]
[111]
[111]
[111]
[111]
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Chapter 3, Problem 37
What 110 -type directions lie on the (111) plane of a cubic unit cell? Draw those directions in an FCC unit
cell. Can you identify a special quality of these directions?
Chapter 3, Solution 37
[0 1 1] , [0 1 1] , [ 1 10] , [1 1 0] , [ 101] , [10 1]
These directions connect at the corners.
Chapter 3, Problem 38
What 111 -type directions lie on the (110) plane of a BCC unit cell? Draw those directions in a unit cell.
Can you identify a special quality of these directions?
Chapter 3, Solution 38
[1 1 1] , [ 1 11] , [1 1 1] , [ 1 1 1]
These directions intersect at the center of the cell
Chapter 3, Problem 39
Draw in unit cubes the crystal planes that have the following Miller indices:
(a) (1 1 1 ) (c) (121 ) (e) (321) (g) (201 ) (i) (232) (k) (312)
(b) (102) (d) (213) (f) (302) (h) (212) (j) (133) (l) (331 )
[ 1 1 1]
[1 1 1]
[1 1 1]
[ 1 0 1]
[0 1 1 ]
[ 1 10]
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71
Chapter 3, Solution 39
Chapter 3, Problem 40
What are the Miller indices of the cubic crystallographic planes shown in Fig. P3.40
Figure P3.40
z
2
3
a
b
d
a
c d
b
c
(a) (b)
y
x
z
y
x
1
3
1
3
3
4
2
3
2
3
1
2
1
3
1
3
1
4
3
4
a. For ( 1 1 1) reciprocals
are: x = 1, y = -1, z = -1
b. For ( 102) reciprocals
are: x = 1, y = ¥, z =
½
c. For ( 1 2 1) reciprocals
are: x = 1, y = -½ , z = -1
-1
-1
+1
(0, 0, 0)
(0, 0, 0)
+1
-⅓

d. For (213) reciprocals are:
x = ½ , y = 1, z = -⅓
e. For (321) reciprocals
are: x = ⅓ , y = -½ , z = 1
(0, 0, 0)
+1

+⅓
f. For (302) reciprocals are:
x = ⅓ , y = ∞, z = -½

(0, 0, 0)
+⅓

• •

+1

(0, 0, 0) •
-1
-½ (0, 0, 0)
+1

z
y
x
(1 1 1) (102) (1 2 1)
(213)
(321)
(302)
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72
Chapter 3, Solution 40
Miller Indices for Figure P3.40(a)
Plane a based on (0, 1, 1) as origin Plane b based on (1, 1, 0) as origin
Planar Intercepts Reciprocals of Intercepts Planar Intercepts Reciprocals of Intercepts
x = ∞
1
0
x
= x = -1
1
1
x
=-
y = -1
1
1
y
=- 5
12
y
= –
1 12
y 5
= –
1
4
z =-
1
4
z
=- z = ∞
1
0
z
=
The Miller indices of plane a are (0 1 4). The Miller indices of plane b are (5 120) .
b
x b
z
y
a

½

¾


c
d
(a) ¾ z
y
(b) ¼
½


a
d
c
x ⅔
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the prior written consent of McGraw-Hill Education.
73
Plane c based on (1, 1, 0) as origin
Plane d based on (0, 0, 0) as origin
Planar Intercepts Reciprocals of Intercepts Planar Intercepts Reciprocals of Intercepts
x = ∞
1
0
x
= x = 1
1
1
x
=
y = -1
1
1
y
=- y = 1
1
1
y
=
1
3
z =
1
3
z
=
2
3
z =
1 3
z 2
=
The Miller indices of plane c are (0 1 3). The Miller indices of plane d are (2 2 3).
Miller Indices for Figure P3.40(b)
Plane a based on (1, 0, 1) as origin Plane b based on (0, 1, 1) as origin
Planar Intercepts Reciprocals of Intercepts Planar Intercepts Reciprocals of Intercepts
x = -1
1
1
x
=- x = 1
1
1
x
=
y = ∞
1
0
y
= y = -1
1
1
y
=-
1
3
z =-
1
3
z
=-
2
3
z =-
1 3
z 2
=-
The Miller indices of plane a are (1 03) . The Miller indices of plane b are (223).
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74
Plane c based on (0, 1, 0) as origin Plane d based on (0, 1, 0) as origin
Planar Intercepts Reciprocals of Intercepts Planar Intercepts Reciprocals of Intercepts
x = 1
1
1
x
= x = 1
1
1
x
=
5
12
y
= –
1 12
y 5
= – y = -1
1
1
y
=-
z = ∞
1
0
z
=
1
2
z =
1
2
z
=
The Miller indices of plane c are (5 120) . The Miller indices of plane d are (1 1 2).
Chapter 3, Problem 41
What are the {100} family of planes of the cubic system? Draw those planes in a BCC unit cell and show all
atoms whose centers are intersected by the planes. What is your conclusion?
Chapter 3, Solution 41
(1 0 0) , (01 0) , (001) , (1 00), (01 0), (001 )
(100) (101)
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75
These planes make up the sides of the unit cell, so none of those planes intersect the
body-centered atom
Chapter 3, Problem 42
Draw the following crystallographic planes in a BCC unit cell and list the position of the atoms whose
centers are intersected by each of the planes:
(a) (010) (b) (011) (c) (111)
(010) (0 10)
(001) (100)
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the prior written consent of McGraw-Hill Education.
76
Chapter 3, Solution 42
Chapter 3, Problem 43
Draw the following crystallographic planes in an FCC unit cell and list the position coordinates of the atoms
whose centers are intersected by each of the planes:
(a) (010) (b) (011) (c) (111)
(010) plane.
Positions of atoms
intersected by plane:
(1,1,0), (1,1,1), (1,1,0),
(1,1,1)
(011) plane.
Positions of atoms
intersected by plane:
(1,1,0) (1,0,1) (0,1,0), (0,0,1)
(0,0,1) (1/2,1/2,1/2)
(111) plane.
Positions of atoms
intersected by plane:
(1,0,0) (0,1,0) (0,0,1)
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the prior written consent of McGraw-Hill Education.
77
Chapter 3, Solution 43
Chapter 3, Problem 44
A cubic plane has the following axial intercepts:
1 2 1
, ,
3 3 2
a = b =- c = . What are the Miller indices of this
plane?
Chapter 3, Solution 44
Given the axial intercepts of (⅓,-⅔, ½), the reciprocal intercepts are:
1 1 3 1
3, , 2.
x y 2 z
= =- =
Multiplying by 2 to clear the fraction, the Miller indices are (6 3 4).
Chapter 3, Problem 45
A cubic plane has the following axial intercepts:
1 1 2
, ,
2 2 3
a =- b =- c = . What are the Miller indices of
this plane?
(010) plane.
Positions of atoms
intersected by plane:
(1,1,0) (1,1,1) (0,1,0), (0,1,1)
(1/2, 1, ½)
(011) plane.
Positions of atoms
intersected by plane:
(1,1,0) (1,0,1) (1,1,0) (0,0,1)
(111) plane.
Positions of atoms
intersected by plane:
(1,0,0) (0,1,0) (0,0,1) (1/2, ½, 0)
(½, 0, ½) (0, ½, ½)
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the prior written consent of McGraw-Hill Education.
78
Chapter 3, Solution 45
Given the axial intercepts of (-½,-½, ⅔), the reciprocal intercepts are:
1 1 1 3
2 , 2 ,
x y z 2
=- =- = .
Multiplying by 2, the Miller indices are (4 4 3).
Chapter 3, Problem 46
Determine the Miller indices of the cubic crystal plane that intersects the following position coordinates:
( 1 ) ( 1 3 ) ( 1 )
2 2 4 2 1, ,1; ,0, ; 1,0, .
Chapter 3, Solution 46
After locating the three position coordinates, connect points b and c and extend the line to point d.
Complete the plane by connecting point d to a and a to c. Using
(1, 0, 1) as the plane origin, x = -1, y = ½ and z = -½. The intercept reciprocals then become
1 1 1
1, 2, 2.
x y z
=- = =- The Miller indices are(1 2 2).
Chapter 3, Problem 47
Determine the Miller indices of the cubic crystal plane that intersects the following position coordinates:
( 1 ) ( ) ( 1 1 )
2 24 0,0, ; 1,0,0 ; , ,0 .
(1, 0, 1)
b
a
• c
• •
(0, 0, 0)
(½, 0, ¾)
• •
(1, 0, ½,) •
(1, ½, 1)
d
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the prior written consent of McGraw-Hill Education.
79
Chapter 3, Solution 47
After locating the three position coordinates, connect points b and c and extend the line to point d.
Complete the plane by connecting point d to a and a to b. Using
(0, 0, 0) as the plane origin, x = 1, y = ½ and z = ½. The intercept reciprocals are thus
1 1 1
1, 2, 2
x y z
= = = .
The Miller indices are therefore (1 2 2).
Chapter 3, Problem 48
Rodium is FCC and has a lattice constant a of 0.38044 nm. Calculate the following interplanar spacings:
(a) d111 (b) d200 (c) d220
Chapter 3, Solution 48
(a) 111 2 2 2
0.38044 nm 0.38044 nm
1 1 1 3
d = = =
+ +
0.220 nm
(b) 200 2 2 2
0.38044 nm 0.38044 nm
2 0 0 4
d = = =
+ +
0.190 nm
(c) 220 2 2 2
0.38044 nm 0.38044 nm
2 2 0 8
d = = =
+ +
0.135 nm
Chapter 3, Problem 49
Tungsten is BCC and has a lattice constant a of 0.31648 nm. Calculate the following interplanar spacings:
(a) d110 (b) d220 (c) d310
d
b
a
c

(0, ½, 0) •
(0, 0, 0)
(1, 0, 0)

 

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